Brian M. Stoltz - Publications

Sun AW, Bulterys PL, Bartberger MD, Jorth PA, O'Boyle BM, Virgil SC, Miller JF, Stoltz BM. Incorporation of a chiral gem-disubstituted nitrogen heterocycle yields an oxazolidinone antibiotic with reduced mitochondrial toxicity. Bioorganic & Medicinal Chemistry Letters. PMID 31383589 DOI 10.1016 j.bmcl.2019.07.024 0.96 2019Cited by 172The Thiopyran Route to Polypropionates Enantioselective supporting information of alexy virgil bartberger and(6S,7S,8S,9R,10S)-()-Membrenone B was synthesized in nine steps (9.4% overall yield) beginning with two-directional aldol coupling of tetrahydro-4H-thiopyran-4-one with racemic 1,4-dioxa-8-thiaspiro[4.5]decane-6-carboxaldehyde. The first aldol reaction occurs with dynamic kinetic resolution to give a single adduct (>98% ee). The second aldol reaction is highly diastereoselective (three of supporting information of alexy virgil bartberger and

Cited by 9Enantioselective Decarboxylative Alkylation Reactions supporting information of alexy virgil bartberger and

Nov 14, 2011 · Aurapat Ngamnithiporn, Toshihiko Iwayama, Michael D. Bartberger, Brian M. Stoltz, Enantioselective synthesis of highly oxygenated acyclic quaternary center-containing building blocks via palladium-catalyzed decarboxylative allylic alkylation of cyclic siloxyketones , Chemical Science, 10.1039 D0SC04383D, (2020).Complimentary and personal copy42 2018 © THIEME STUTTGART NEW YORK E. J.ALEXY, S. C.VIRGIL, M. D.BARTBERGER, B. M.STOLTZ* (CALIFORNIA INSTITUTE OF TECHNOLOGY, PASADENA AND AMGEN, INC supporting information of alexy virgil bartberger andEnantioselective Alkylation of Acyclic ,Disubstituted supporting information of alexy virgil bartberger andSkip to Article Information; Search within. Search term. Advanced Search Citation Search. Search term. Advanced Search Citation Search supporting information of alexy virgil bartberger and

Enantioselective Pd-Catalyzed Decarboxylative Allylic supporting information of alexy virgil bartberger and

A catalytic, enantioselective decarboxylative allylic alkylation of 4-thiopyranones is reported. The -quaternary 4-thiopyranones produced are challenging to access by standard enolate alkylation owing to facile ring-opening -sulfur elimination. In addition, reduction of the carbonsulfur bonds provides access to elusive acyclic -quaternary ketones.Enantioselective Pd-Catalyzed Decarboxylative Allylic supporting information of alexy virgil bartberger andBy Eric J. Alexy (2613202), Scott C. Virgil (1323939), Michael D. Bartberger (1261599) and Brian M. Stoltz (1297560)Enantioselective Pd-Catalyzed Decarboxylative Allylic supporting information of alexy virgil bartberger andOct 06, 2017 · Alexy EJ(1), Virgil SC(1), Bartberger MD(2), Stoltz BM(1). Author information (1)Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of

Enantioselective Pd-Catalyzed Decarboxylative Allylic supporting information of alexy virgil bartberger and

Supporting Information for Alexy, Virgil, Bartberger, and Stoltz SI3 General Procedure for Pd-Catalyzed Allylic Alkylation Reactions In a nitrogen-filled glovebox, Pd 2(pmdba) 3 (1.0 mol %, 2.2 mg) and (R,R)-L5 (2.4 mol %, 3.9 mg) were added to a 1 dram vial Enhancing Effects of Salt Formation on Catalytic Activity supporting information of alexy virgil bartberger andAbstract Asymmetric hydrogenation of 1 and 3substituted and 1,3disubstituted isoquinolinium chlorides using triply halidebridged dinuclear iridium complexes [{Ir(H)(diphosphine)}2(Cl)3]Cl has supporting information of alexy virgil bartberger andEric J. Alexy Journal of Chemical & Engineering Data supporting information of alexy virgil bartberger andBy Eric J. Alexy, Scott Virgil, Brian M. Stoltz, Michael D. Bartberger. pubs.acs Warren and Katharine Schlinger Laboratory for Chemistry and Chemical Engineering, Division of Chemistry and Chemical Engineering, California Institute of Technology supporting information of alexy virgil bartberger and

Letters - cdn-pubs.acs

This website uses cookies to improve your user experience. By continuing to use the site, you are accepting our use of cookies. Read the ACS privacy policy. CONTINUEPalladium-catalyzed enantioselective decarboxylative supporting information of alexy virgil bartberger andThe first enantioselective palladium-catalyzed decarboxylative allylic alkylation of fully substituted N-acyl indole-derived enol carbonates forming acyclic all-carbon quaternary stereocenters is reported. Excellent yields up to 99% and enantioselectivities up to 98% ee are obtained through the use of a newPublications The Stoltz GroupAurapat Ngamnithiporn, Toshihiko Iwayama, Michael D. Bartberger, and Brian M. Stoltz Chem. Sci. 2020, in press. 274. Efficient Synthesis of Geminal-Dialkyl Dienes for Olefin Metathesis Polymerization

Scott C. Virgil's research works California Institute of supporting information of alexy virgil bartberger and

Scott C. Virgil's 77 research works with 1,957 citations and 2,873 reads, including Cover Feature A Facile Method for the Separation of Methionine Sulfoxide Diastereomers, Structural Assignment supporting information of alexy virgil bartberger andSupporting Information of Alexy, Virgil, Bartberger, and supporting information of alexy virgil bartberger andSupporting Information of Alexy, Virgil, Bartberger, and Stoltz SI26 13C NMR (100 MHz, CDCl 3) of compound 2c. Infrared spectrum (Thin Film, NaCl) of compound 2c.Synthesis, Characterization, and Optimization for in Vivo supporting information of alexy virgil bartberger andBis-arylidenecycloalkanones structurally related to the nonselective isopeptidase inhibitor G5 were synthesized and tested for cytotoxic activity against glioblastoma cells. Cytotoxicities correlate well with Hammett constants for substituted arylidene groups, confirming the proposed inhibition mechanism. A new inhibitor (2c) based on the 4-hydroxycyclohexanone scaffold, which favors supporting information of alexy virgil bartberger and

Synthesis, Characterization, and Optimization for in Vivo supporting information of alexy virgil bartberger and

Find more information about Crossref citation counts. supporting information of alexy virgil bartberger and » Supporting Information Supporting Information Get e-Alerts. Download Hi-Res Image Download to MS-PowerPoint Cite This J. Med. Chem. 2015 58 4 1691 supporting information of alexy virgil bartberger and Eric J. Alexy, Scott C. Virgil, Michael D. Bartberger, and Brian M. Stoltz . supporting information of alexy virgil bartberger andThe Stoltz Group - Publications[Supporting Information]. "Stereospecific Overman Rearrangement of Substituted Cyclic Vinyl Bromides Access to Fully Substituted -Amino Ketones" Álvaro Velasco-Rubio, Eric J. Alexy, Makoto Yoritate, Austin C. Wright, and Brian M. Stoltz. Org. Lett. 2019, Article ASAP. [Supporting Information].The Thiopyran Route to Polypropionates Enantioselective supporting information of alexy virgil bartberger and(6S,7S,8S,9R,10S)-()-Membrenone B was synthesized in nine steps (9.4% overall yield) beginning with two-directional aldol coupling of tetrahydro-4H-thiopyran-4-one with racemic 1,4-dioxa-8-thiaspiro[4.5]decane-6-carboxaldehyde. The first aldol reaction occurs with dynamic kinetic resolution to give a single adduct (>98% ee). The second aldol reaction is highly diastereoselective (three of supporting information of alexy virgil bartberger and

Unusual allylpalladium carboxylate complexes supporting information of alexy virgil bartberger and

Jan 01, 2009 · Virgil SC, Stoltz BM. Author information. Affiliations. 1 author. 1. The Arnold and Mabel Beckman Laboratories of Chemical Synthesis and the Caltech Center for Catalysis and Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 E. California Boulevard MC 164-30, Pasadena, CA 91125, USA supporting information of alexy virgil bartberger and

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